Well, each Chipset/Tileset is 16x16 pixels.. there's 30 chips across, 16 chips down. There's really no other way to explain that.. there are different things a chip/tile will do depending on where it is, so I'll just have to refer you to the Help file because I don't want to just copy/paste.

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Battle Animations -
480x480 pixels total. Each animation is 96x96, allowing for 25 frames per picture. Just position them like you normally would.. I've never used Paint Shop Pro, so I'm not sure if it has a position label or not (something like x=100, y=40) but if it does, make good use of it.